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Authors
Info
Carlin Geor Malar1,
M. Seenuvasan2, 3* and
K. Sathishkumar4
1Department of
Biotechnology, Rajalakshmi Engineering College, Chennai-602 105, India
2Department of
Petrochemical Engineering, SVS College of Engineering, Coimbatore-642 109,
India
3Department of
Chemical Engineering, Hindusthan College of Engineering and Technology,
Coimbatore-641 032, India
4Department of
Chemical Engineering, SSN College of Engineering, Chennai-603 110, India
*Corresponding
Author Email :
msvasan.chem@gmail.com
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Abstract
Aim: In this study, the
adsorption ability of surface modified magnetite nanoparticles was
investigated.
Methodology: Magnetite
nanoparticles (MNs) were prepared by solvothermal method and the surface was
modified by 3-(2-Aminoethylamino) propyldimethoxymethylsilane (AEAPS) and
utilized as an adsorbent against nickel ions in aqueous solution. Characteristic
studies were performed to study the various properties of MNs before and
after surface modification. Ni2+ adsorption was studied
as a function of contact time, initial concentration and adsorbent dosage at
neutral pH and constant temperature (100 ?C).
Results: Presence of
required characteristic peaks in IR spectrum and X-ray diffraction (XRD)
patterns revealed formation of magnetite and surface modification. Spherical
and defined morphology of surface modified MNs (aMNs) was studied through
electron micrographs. The kinetic data obeyed the first-order equation.
Interpretation: Surface modified
MNs can be used for the efficient removal of Ni2+ from
aqueous solution. Also, the kinetics study revealed the adsorption capacity
of MNs against nickel ions.
Key words: Adsorption, Kinetics, Magnetite, Nanoparticles, Nickel
ions
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